Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Effects of NaOH and Ethanol on the Solubility of Disodium Decanedioate in Water

Kang, J.[Jia], Xia, Q.[Qing], Wang, L.-X.[Ling-Xin], Du, M.-X.[Ming-Xing], Zhang, F.-B.[Feng-Bao], Zhang, G.-L.[Guo-Liang]
J. Chem. Eng. Data 2012, 57, 3, 994-999
ABSTRACT
To investigate the effects of NaOH and ethanol on the solubility of disodium decanedioate in water, the solubilities of disodium decanedioate in two aqueous solutions (aqueous NaOH solutions and aqueous ethanol solutions) were determined in a temperature range of (284 to 345) K. The solute-free mole fraction of NaOH and ethanol in the solvent mixtures extended from 0 to 0.084 and 0 to 0.472, respectively. With the increase of the mole fractions of ethanol (or NaOH) in solvent mixtures, the solubilities decreased obviously. Alcohol-out and alkali-out phenomena could be evidently observed, between which the alkali-out effect was more prominent. The determined data were correlated with the new electrolyte nonrandom two-liquid (E-NRTL) model, and the root-mean-square deviations of solubility temperature varied from (0.26 to 0.91) K.
Compounds
# Formula Name
1 HNaO sodium hydroxide
2 C2H6O ethanol
3 C10H16Na2O4 sodium decanedioate
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • laser technique
  • 12
  • POMD
  • 2
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • laser technique
  • 66
  • POMD
  • 1
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Solvent: Mole fraction - 1; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 3
  • laser technique
  • 53