Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Partial Molar Volumes and Partial Molar Isentropic Compressions of Three Polyhydric Alcohols Derived from Propane at Infinite Dilution in Water at Temperatures T = (278 to 318) K and Atmospheric Pressure

Katrinak, T.[Tomas], Hnedkovsky, L.[Lubomir], Cibulka, I.[Ivan]
J. Chem. Eng. Data 2012, 57, 4, 1152-1159
ABSTRACT
Density and speed of sound data for dilute aqueous solutions of three polyhydric alcohols derived from propane (propane-1,2-diol, propane-1,3-diol, propane-1,2,3-triol) were obtained using the Anton Paar DSA 5000 vibrating-tube densimeter and sound analyzer in the temperature range from (278.15 to 318.15) K and at atmospheric pressure. Partial molar volumes at infinite dilution (standard molar volumes) and partial molar isentropic compressions at infinite dilution (standard molar isentropic compressions) were calculated from the measured data.
Compounds
# Formula Name
1 C3H8O2 1,2-propanediol
2 H2O water
3 C3H8O2 propan-1,3-diol
4 C3H8O3 glycerol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Sing-around technique in a fixed-path interferometer
  • 106
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 106
  • POMD
  • 3
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Sing-around technique in a fixed-path interferometer
  • 106
  • POMD
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 106
  • POMD
  • 4
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Sing-around technique in a fixed-path interferometer
  • 107
  • POMD
  • 4
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 107