Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Evaluation of the Performance of Four Solvents for the Liquid Liquid Extraction of Acrylic Acid from Water

ATTIA, A.[Afef], Mutelet, F.[Fabrice], Solimando, R.[Roland], JEDAY, M. R.[Med Razzak]
J. Chem. Eng. Data 2012, 57, 8, 2114-2120
ABSTRACT
n this work, experimental liquid liquid equilibrium data for four ternary systems containing {water + acrylic acid + solvent} were determined at 298.15 K and atmospheric pressure. The experimental data were also compared with the values correlated by the nonrandom two-liquid (NRTL) and universal quasichemical (UNIQUAC) models. Good quantitative agreement was obtained with these models. In general, the average deviation from the NRTL model is slightly greater than those from the UNIQUAC model. The reliability of the experimental tie-line data was confirmed by using the Othmer Tobias correlation.
Compounds
# Formula Name
1 H2O water
2 C3H4O2 propenoic acid
3 C6H12O 4-methylpentan-2-one
4 C7H8 toluene
5 C8H10 1,2-dimethylbenzene
6 C8H10 1,4-dimethylbenzene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 15
  • POMD
  • 2
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 9
  • POMD
  • 2
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid mixture 2
  • Mass fraction - 3; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Vibrating tube method
  • 9
  • POMD
  • 2
  • 3
  • 1
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 15
  • POMD
  • 2
  • 3
  • 1
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 1 ; Liquid mixture 2
  • Mass fraction - 3 ; Liquid mixture 2
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • Titration method
  • Titration method
  • 9
  • POMD
  • 2
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 18
  • POMD
  • 2
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 12
  • POMD
  • 2
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid mixture 2
  • Mass fraction - 4; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Vibrating tube method
  • 12
  • POMD
  • 2
  • 4
  • 1
  • Mass fraction - 4 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 18
  • POMD
  • 2
  • 4
  • 1
  • Mass fraction - 4 ; Liquid mixture 1
  • Mass fraction - 1 ; Liquid mixture 2
  • Mass fraction - 4 ; Liquid mixture 2
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • Titration method
  • Titration method
  • 12
  • POMD
  • 2
  • 5
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 17
  • POMD
  • 2
  • 5
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 10
  • POMD
  • 2
  • 5
  • 1
  • Mass density, kg/m3 ; Liquid mixture 2
  • Mass fraction - 5; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Vibrating tube method
  • 10
  • POMD
  • 2
  • 5
  • 1
  • Mass fraction - 5 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 17
  • POMD
  • 2
  • 5
  • 1
  • Mass fraction - 5 ; Liquid mixture 1
  • Mass fraction - 1 ; Liquid mixture 2
  • Mass fraction - 5 ; Liquid mixture 2
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • Titration method
  • Titration method
  • 10
  • POMD
  • 2
  • 6
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 14
  • POMD
  • 2
  • 6
  • 1
  • Mass density, kg/m3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Vibrating tube method
  • 7
  • POMD
  • 2
  • 6
  • 1
  • Mass density, kg/m3 ; Liquid mixture 2
  • Mass fraction - 6; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Vibrating tube method
  • 7
  • POMD
  • 2
  • 6
  • 1
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 14
  • POMD
  • 2
  • 6
  • 1
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 1 ; Liquid mixture 2
  • Mass fraction - 6 ; Liquid mixture 2
  • Mass fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • Titration method
  • Titration method
  • 7