Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Carbon Dioxide in Water and Aqueous Solution Containing Sodium Hydroxide at Temperatures from (293.15 to 393.15) K and Pressure up to 5 MPa: Experimental Measurements

Lucile, F.[Floriane], Cezac, P.[Pierre], Contamine, F.[Francois], Serin, J.-P.[Jean-Paul], Houssin, D.[Deborah], Arpentinier, P.[Philippe]
J. Chem. Eng. Data 2012, 57, 3, 784-789
ABSTRACT
New experimental solubility data for carbon dioxide in pure water and in aqueous solution containing sodium hydroxide in the temperature range (293.15 to 393.15) K and pressures up to 5 MPa are presented in this work. A new experimental apparatus based on an equilibrium cell with a constant volume allowing the measurement of carbon dioxide solubility is presented. The liquid phase composition at the thermodynamic equilibrium is determined by an analytical method (ion chromatography) and a static synthetic method. The CO2 + water system is used to validate the experimental apparatus; therefore data obtained are compared with literature data.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 HNaO sodium hydroxide
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 30
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Amount concentration (molarity), mol/dm3 - 2; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 21