Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Excess Molar Volumes of 2,4,6,8-Tetramethylcyclotetrasiloxane with Benzene, Toluene, and Xylene at T = (288.15, 298.15, and 308.15) K

Dong, H.[Hong], Yue, Y.[Yan], Wu, C.[Chuan], Lai, G.[GuoQiao]
J. Chem. Eng. Data 2012, 57, 4, 1050-1056
ABSTRACT
Densities of binary mixtures of 2,4,6,8-tetramethylcyclotetrasiloxane with benzene, toluene, o-xylene, m-xylene, and p-xylene have been determined at temperatures of (288.15, 298.15, and 308.15) K using an Anton Paar DMA 4500 oscillating u-tube densitometer. Excess molar volumes have been derived from the density data. The experimental data were satisfactorily fitted to the Redlich Kister equation and the Legendre polynomials.
Compounds
# Formula Name
1 C4H16O4Si4 2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetroxatetrasilocane
2 C6H6 benzene
3 C7H8 toluene
4 C8H10 1,2-dimethylbenzene
5 C8H10 1,3-dimethylbenzene
6 C8H10 1,4-dimethylbenzene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54
  • POMD
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54
  • POMD
  • 5
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54
  • POMD
  • 6
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 54