Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Refractive index of liquid D2O for visible wavelengths

Odhner, H.[Hosanna], Jacobs, D. T.
J. Chem. Eng. Data 2012, 57, 1, 166-168
ABSTRACT
The index of refraction for D2O at common wavelengths was measured for several temperatures at atmospheric pressure. While heavy water fs refractive index was precisely measured decades ago using the transition lines of elements, those wavelengths are seldom used now that inexpensive lasers provide a range of available wavelengths. We review those measurements, note some inconsistencies between research groups, and fit the best of the literature data to a simple equation that allows an easy calculation for the refractive index of D2O at any visible wavelength and between 5 and 95 C. We then compare to our measured refractive index values for three He ]Ne laser wavelengths (543.5, 594.1, and 632.8 nm) over a temperature range from 15 to 65C and find good agreement.
Compounds
# Formula Name
1 D2O water-d2
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Refractive index (other wavelength) ; Liquid
  • Temperature, K; Liquid
  • Wavelength, nm; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Minimum Deviation technique
  • 33