Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosity Measurements of the Ionic Liquid Trihexyl(tetradecyl)phosphonium Dicyanamide [P6,6,6,14][dca] Using the Vibrating Wire Technique

Diogo, J. C. F.[Joao C.F.], Caetano, F. J. P.[Fernando J.P.], Fareleira, J. M. N. A.[Joao M.], Wakeham, W. A.[William A.]
J. Chem. Eng. Data 2012, 57, 4, 1015-1025
ABSTRACT
The paper reports measurements of the viscosity of the ionic liquid trihexyl(tetradecyl)phosphonium dicyanamide ([P6,6,6,14][dca]) by means of a vibrating wire viscometer; the measurements have been carried out to demonstrate the applicability of the method to studies on electrically conducting liquids. To the knowledge of the authors, the present work reports only the second measurements of the viscosity of ionic liquids, using the vibrating wire method, ever published in the literature. The measurements were carried out at near ambient temperature at atmospheric pressure so that they can be compared with measurements made on the same sample using measurement techniques of previously proven validity. For this purpose measurements have also been carried out with two Ubbelohde capillary viscometers. Density measurements were undertaken using a U-tube Anton Paar density meter. All of the viscosity results reported here are mutually consistent within the estimated uncertainty of +- 2 % of the vibrating wire measurements, which confirms the applicability of the vibrating wire technique. However, the other viscosity literature data for of the same liquid deviate from the present results by more than the mutual estimated uncertainties of the measurements which may arise mainly from the different purities of the two samples.
Compounds
# Formula Name
1 C34H68N3P tetradecyl(trihexyl)phosphonium dicyanamide
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating wire viscometry
  • 6
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 26
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 6