Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric Properties for the Binary Systems Hexane + Octane and Hexane + Decane at High Temperatures and Pressures

Quevedo-Nolasco, R.[Rodolfo], Cruz-Hernandez, L. A. d. l.[Luis A. de la], Galicia-Luna, L. A.[Luis A.], Elizalde-Solis, O.[Octavio]
J. Chem. Eng. Data 2011, 56, 11, 4226-4234
ABSTRACT
Volumetric properties (p, ?, T, x1) of two binary linear alkane systems are reported in the temperature range of (313 to 363) K and up to 25 MPa. Binary mixtures were prepared at compositions of (x1 = 0.1654, 0.2199, 0.5749, 0.7995, and 0.9308) for hexane (1) + octane (2) and hexane (1) + decane (2) at (x1 = 0.0456, 0.2185, 0.4968, 0.7524, and 0.8991) in mole fraction. Experimental densities were measured in a vibrating-tube densimeter, DMA HPM from Anton Paar, using water and nitrogen as reference fluids. The excess molar volumes, isobaric thermal expansivities, and isothermal compressibilities for these systems were computed from experimental data using a six-parameter modified Toscani and Szwarc equation.
Compounds
# Formula Name
1 C6H14 hexane
2 C8H18 octane
3 C10H22 decane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Vibrating tube method
  • 750
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Vibrating tube method
  • 750