ABSTRACT

Excess molar enthalpies are reported for mixtures of (+-)-2,6-dimethyl-2,7-octadien-6-ol (linalool) with ethanol, propan-1-ol, propan-2-ol, and butan-1-ol at the temperatures (283.15, 298.15, 313.15, and 328.15) K and atmospheric pressure, covering the whole composition range. The values of excess molar enthalpy at each temperature have been fitted using approximants of Pade. Most of the mixtures show negative values of the excess enthalpy, indicating the formation of attractive interactions, mainly hydrogen bonds, between the molecules of linalool and molecules of the different alkanols.

Compounds

#	Formula	Name
1	C10H18O	3,7-dimethyl-1,6-octadien-3-ol
2	C3H8O	propan-1-ol
3	C4H10O	butan-1-ol
4	C3H8O	propan-2-ol
5	C2H6O	ethanol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	5 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	44
POMD	2 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	44
POMD	4 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	48
POMD	3 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	44

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

ACSExcess Molar Enthalpies of Mixtures of (+-)-Linalool with Several Alkanols

Mainar, A. M.[Ana M.], Garcia-Abarrio, S. M.[Sandra M.], Palavra, A. M. F.[Antonio M. F], Urieta, J. S.[Jose S.], Pardo, J. I.[Juan I.]

ABSTRACT