ABSTRACT

Data are presented on the solubilities, densities, and refractive indices of the four ternary systems glycerin + MCl + H2O (M = Na, K, Rb, Cs) at (298.15 and 308.15) K and atmospheric pressure. The mass fraction of glycerin in the salt-free mixed solvent extends from 0 to 1.0. In all cases, the experiment values of solubilities were found to decrease with an increase of the concentration of glycerin. The measured solubilities, densities, and refractive indices of saturated solutions as well as densities and refractive indices of unsaturated solutions were fitted with available empirical correlations, respectively.

Compounds

#	Formula	Name
1	ClRb	rubidium chloride
2	ClCs	cesium chloride
3	C3H8O3	glycerol
4	ClNa	sodium chloride
5	ClK	potassium chloride
6	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	4 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Standard Abbe refractometry	2
POMD	4 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Vibrating tube method	2
POMD	4 6	Mass fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Titration method	2
POMD	3 4	Mass fraction - 4 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Titration method	2
POMD	5 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Standard Abbe refractometry	2
POMD	5 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Vibrating tube method	2
POMD	5 6	Mass fraction - 5 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Titration method	2
POMD	3 5	Mass fraction - 5 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Titration method	2
POMD	6 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Standard Abbe refractometry	2
POMD	6 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Vibrating tube method	2
POMD	6 1	Mass fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	2
POMD	3 1	Mass fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	2
POMD	2 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Standard Abbe refractometry	2
POMD	2 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Vibrating tube method	2
POMD	2 6	Mass fraction - 2 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Titration method	2
POMD	3 2	Mass fraction - 2 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Titration method	2
POMD	3 4 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Standard Abbe refractometry	20
POMD	3 4 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Vibrating tube method	20
POMD	3 4 6	Mass fraction - 4 ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 4	Titration method	22
POMD	3 4 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	93
POMD	3 4 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	93
POMD	3 5 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Standard Abbe refractometry	20
POMD	3 5 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Vibrating tube method	20
POMD	3 5 6	Mass fraction - 5 ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 5	Titration method	22
POMD	3 5 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	83
POMD	3 5 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	83
POMD	3 6 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Standard Abbe refractometry	20
POMD	3 6 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Vibrating tube method	20
POMD	3 6 1	Mass fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Titration method	22
POMD	3 6 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	60
POMD	3 6 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	60
POMD	3 2 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Standard Abbe refractometry	20
POMD	3 2 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Vibrating tube method	20
POMD	3 2 6	Mass fraction - 2 ; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 2	Titration method	22
POMD	3 2 6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	89
POMD	3 2 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mass fraction - 3; Liquid Mass fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	89

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities, Densities, and Refractive Indices for the Ternary Systems Glycerin + MCl + H2O (M = Na, K, Rb, Cs) at (298.15 and 308.15) K

Meng, R.[Rui], Li, S.[Shu'ni], Zhai, Q.[Quanguo], Hu, M.[Mancheng], Jiang, Y.[Yucheng], Lei, H.[Hong], Zhang, H.[Huiying]

ABSTRACT