ABSTRACT

Conductivities were measured for the ternary systems Y(NO3)3 + Ce(NO3)3 + H2O, Y(NO3)3 + Nd(NO3)3 + H2O, and Ce(NO3)3 + Nd(NO3)3 + H2O and their binary subsystems Y(NO3)3 + H2O, Ce(NO3)3 + H2O, and Nd(NO3)3 + H2O at (293.15, 298.15, and 308.15) K. The measured conductivities were used to test the generalized Young s rule and the semi-ideal solution theory. The comparison results show that the generalized Young s rule and the semi-ideal solution theory can yield good predictions for the conductivities of the ternary electrolyte solutions, implying that the conductivities of aqueous solutions of (1:3 + 1:3) electrolyte mixtures can be well predicted from those of their constituent binary solutions by the simple equations.

Compounds

#	Formula	Name
1	H2O	water
2	N3O9Y	yttrium nitrate
3	CeN3O9	cerium nitrate
4	N3NdO9	neodymium(III) nitrate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2	Electrical conductivity, S/m ; Liquid	Molality, mol/kg - 2; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	METLER TOLEDO SevenEasy conductivity meter	21
POMD	1 3	Electrical conductivity, S/m ; Liquid	Molality, mol/kg - 3; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	METLER TOLEDO SevenEasy conductivity meter	21
POMD	1 4	Electrical conductivity, S/m ; Liquid	Molality, mol/kg - 4; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	METLER TOLEDO SevenEasy conductivity meter	21
POMD	1 3 2	Electrical conductivity, S/m ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	METLER TOLEDO SevenEasy conductivity	36
POMD	1 4 2	Electrical conductivity, S/m ; Liquid	Temperature, K; Liquid Molality, mol/kg - 2; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	METLER TOLEDO SevenEasy conductivity	34
POMD	1 4 3	Electrical conductivity, S/m ; Liquid	Temperature, K; Liquid Molality, mol/kg - 3; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	METLER TOLEDO SevenEasy conductivity	36

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Conductivities of the Ternary Systems Y(NO3)3 + Ce(NO3)3 + H2O, Y(NO3)3 + Nd(NO3)3 + H2O, Ce(NO3)3 + Nd(NO3)3 + H2O and Their Binary Subsystems at Different Temperatures

Hu, Y.-F.[Yu-Feng], Peng, X.-M.[Xiao-Ming], Zhang, J.-Z.[Jin-Zhu], Jin, C.-W.[Chuan-Wei]

ABSTRACT