Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Phase Diagrams for Aqueous Two-Phase Systems Containing the 1-Ethyl-3-methylimidazolium Tetrafluoroborate/1-Propyl-3-methylimidazolium Tetrafluoroborate and Trisodium Phosphate/Sodium Sulfite/Sodium Dihydrogen Phosphate at 298.15 K: Experiment and Correlation

Yu, C.[Cuilan], Hu, S.[Shiping], Yan, Y.[Yongsheng], Li, Y.[Yanfang]
J. Chem. Eng. Data 2011, 56, 9, 3577-3584
ABSTRACT
Liquid liquid equilibrium data have been determined for 1-ethyl-3-methylimidazolium tetrafluoroborate ([Emim]BF4)/1-propyl-3-methylimidazolium tetrafluoroborate ([Pmim]BF4) + trisodium phosphate (Na3PO4)/sodium sulfite (Na2SO3)/sodium dihydrogen phosphate (NaH2PO4) aqueous two-phase systems at T = 298.15 K, respectively. Two empirical equations were used to correlate binodal data. The Othmer-Tobias and Bancroft as well as Setschenow-type equations were used to correlate the tie-line data. The results show that good agreement was obtained with the experimental data. The effect of salt on the phase forming ability has been studied based on the effective excluded volume (EEV) values from fitting the binodal data to the binodal model. The binodal curves and EEV both indicate that the salting-out effect of the three salts follow the order Na3PO4 greater than Na2SO3 greater than NaH2PO4, which can also be related to the Gibbs free energy of hydration of the ions (?hydG) and [Pmim]BF4 is easier to be excluded the IL-rich phase than [Emim]BF4.
Compounds
# Formula Name
1 Na3O4P trisodium phosphate
2 H2O water
3 C6H11BF4N2 1-ethyl-3-methylimidazolium tetrafluoroborate
4 Na2O3S sodium sulfite
5 H2NaO4P sodium dihydrogen phosphate
6 C7H13BF4N2 1-propyl-3-methylimidazolium tetrafluoroborate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 29
  • POMD
  • 2
  • 4
  • 3
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 4; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 32
  • POMD
  • 2
  • 4
  • 3
  • Mass fraction - 4 ; Liquid mixture 1
  • Mass fraction - 3 ; Liquid mixture 2
  • Mass fraction - 4 ; Liquid mixture 2
  • Mass fraction - 3; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • Titration method
  • Titration method
  • 3
  • POMD
  • 5
  • 2
  • 3
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 5; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 33
  • POMD
  • 5
  • 2
  • 3
  • Mass fraction - 3 ; Liquid mixture 2
  • Mass fraction - 5 ; Liquid mixture 1
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 5; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Titration method
  • Titration method
  • Titration method
  • 3
  • POMD
  • 1
  • 2
  • 6
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 29
  • POMD
  • 2
  • 4
  • 6
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 4; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 32
  • POMD
  • 2
  • 4
  • 6
  • Mass fraction - 6 ; Liquid mixture 2
  • Mass fraction - 4 ; Liquid mixture 1
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 4; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Titration method
  • Titration method
  • Titration method
  • 3
  • POMD
  • 5
  • 2
  • 6
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 5; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Titration method
  • 33
  • POMD
  • 5
  • 2
  • 6
  • Mass fraction - 5 ; Liquid mixture 2
  • Mass fraction - 6 ; Liquid mixture 1
  • Mass fraction - 5 ; Liquid mixture 1
  • Mass fraction - 6; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Titration method
  • Titration method
  • Titration method
  • 3