Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Equilibrium Phase Densities, Vapor Phase Compositions, and Interfacial Tensions for the Methane + Ethane + n-Pentane System at 294.15 K

Nilssen, H. N.[Hui N.], Fredheim, A. O.[Arne O.], Berg, O. J.[Ole J.], Solbraa, E.[Even], Kvamme, B.[Bjorn]
J. Chem. Eng. Data 2011, 56, 11, 4006-4011
ABSTRACT
The equilibrium phase densities, vapor phase compositions, and interfacial tensions of the ternary mixture (methane + ethane + n-pentane) have been measured simultaneously using the pendant drop technique at 294.15 K. The total mole compositions of the measured ternary mixtures are 50.61 % methane + 8.93 % ethane + 40.46 % n-pentane; 34.20 % methane + 6.04 % ethane + 59.76 % n-pentane; and 17.46 % methane + 3.08 % ethane + 79.40 % n-pentane, respectively. The measured phase densities and vapor phase compositions are compared with calculated equilibrium properties from the GERG2004 equation. No open interfacial tension data for these ternary systems have been reported at any isothermal conditions. The average experimental interfacial tension data can be described with the total deviations of about 3.2 %. The combined standard uncertainty at each experimental condition is calculated on the basis of ISO recommendations.
Compounds
# Formula Name
1 CH4 methane
2 C2H6 ethane
3 C5H12 pentane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Gas
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Pendant drop shape
  • 9
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Gas
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 2; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 2 ; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 9