Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Enthalpy of Solution of Carbon Dioxide in Aqueous Solutions of Monoethanolamine at Temperatures of 322.5 K and 372.9 K and Pressures up to 5 MPa

Arcis, H.[Hugues], Ballerat-Busserolles, K.[Karine], Rodier, L.[Laurence], Coxam, J. -Y.[Jean-Yves]

J. Chem. Eng. Data 2011, 56, 8, 3351-3362

ABSTRACT

The enthalpies of solution (solH) of carbon dioxide (CO2) in two aqueous solutions (w = 0.1500 and w = 0.3000) of monoethanolamine (MEA) have been measured at two temperatures (322.5 K and 372.9 K) and pressures up to 5 MPa. Measurements were carried out by a flow calorimetric technique using a custom-made flow-mixing unit combined with a SETARAM C-80 isothermal differential heat-flux calorimeter. Enthalpies of solution of CO2 (solH) have been obtained as function of loading a (moles CO2/mol amine). Solubility data of the gas into the different absorbent (s) were derived from the enthalpic data.

Compounds

#	Formula	Name
1	C2H7NO	2-aminoethan-1-ol
2	H2O	water
3	CO2	carbon dioxide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2	Mass density, kg/m3 ; Liquid	Mass fraction - 1; Liquid Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	10
POMD	3 1 2	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Mole fraction - 3; Liquid	Temperature, K; Liquid Solvent: Mass fraction - 1; Liquid	Liquid	Flow calorimetry	75
POMD	3 1 2	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Mole fraction - 3; Liquid	Temperature, K; Liquid Mass fraction - 1; Liquid	Liquid	Flow calorimetry	97
POMD	3 1 2	Molar enthalpy of solution, kJ/mol ; Liquid	Pressure, kPa; Liquid Mole fraction - 3; Liquid Temperature, K; Liquid	Mass fraction - 1; Liquid	Liquid	Flow calorimetry	178