Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Phenothiazine in Water, Ethanol, and Propylene Glycol at (298.2 to 338.2) K and Their Binary and Ternary Mixtures at 298.2 K

Ahmadian, S.[Somaieh], Panahi-Azar, V.[Vahid], Fakhree, M. A. A.[Mohammad A. A.], Acree, Jr., W. E.[William E.], Jouyban, A.[Abolghasem]
J. Chem. Eng. Data 2011, 56, 12, 4352-4355
ABSTRACT
The solubilities of phenothiazine in water, ethanol, and propylene glycol were measured at (298.2 to 338.2) K. Also, the solubility of phenothiazine in binary mixtures of ethanol + water, propylene glycol + water, and ethanol + propylene glycol, and the ternary mixture of ethanol + propylene glycol + water was investigated. The van't Hoff equation was used to correlate the solubility of phenothiazine in monosolvents at different temperatures. The solubility values of phenothiazine in binary and ternary mixtures of solvents were calculated using the Jouyban Acree model (Jouyban, A.; Acree, W. E., Jr. J. Chem. Eng. Data2009, 54, 1168 1170). The mean deviation was used as an error criterion. The overall mean deviation of correlated solubility data in monosolvents at different temperatures and in mixed solvents at 298.2 K were 2.8 % and 14.2 %, respectively.
Compounds
# Formula Name
1 C12H9NS 10H-phenothiazine
2 C2H6O ethanol
3 C3H8O2 1,2-propanediol
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • VISOBS
  • 1
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 4
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Density calibration data
  • 5
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 5
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Density calibration data
  • 5
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 5
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Density calibration data
  • 5
  • POMD
  • 3
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 10
  • POMD
  • 3
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Density calibration data
  • 10
  • POMD
  • 2
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 9
  • POMD
  • 2
  • 1
  • 4
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Density calibration data
  • 9
  • POMD
  • 3
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Solvent: Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Pycnometric method
  • 9
  • POMD
  • 3
  • 1
  • 4
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Crystal - 1
  • Density calibration data
  • 9