Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation for the Solubility of Dimethyl 1,4-Cyclohexanedione-2,5-dicarboxylate in Different Solvents at Temperatures from (278.15 to 323.15) K

Chen, Z.-g.[Zhao-guo], Yang, W.-g.[Wen-ge], Hu, Y.-H.[Yong-Hong], Lei, Z.-Y.[Zi-Yu], Wang, Y.-H.[Yao-Han], Wan, W.-Q.[Wen-Qian]
J. Chem. Eng. Data 2011, 56, 5, 2726-2729
ABSTRACT
As an urgent need in the design and upscale of the industrial crystallization process, on the basis of the isothermal saturated method, the solubility of dimethyl 1,4-cyclohexanedione-2,5-dicarboxylate in N,N-dimethylformamide, methanol, 1-propanol, acetonitrile, 2-propanol, ethyl acetate, and acetone was measured at atmospheric pressure. The experimental data were well-correlated with the ?h model. The calculated solubilities show good agreement with the experimental solubility data. To our knowledge, this is the first time the solubilities of dimethyl 1,4-cyclohexanedione-2,5-dicarboxylate are reported.
Compounds
# Formula Name
1 C10H12O6 dimethyl 2,5-dioxocyclohexane-1,4-dicarboxylate
2 C3H7NO dimethylformamide
3 CH4O methanol
4 C3H8O propan-1-ol
5 C2H3N acetonitrile
6 C3H8O propan-2-ol
7 C4H8O2 ethyl acetate
8 C3H6O acetone
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10
  • POMD
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 10