Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of CO2 in Alcohols, Glycols, Ethers, and Ketones at High Pressures from (288.15 to 318.15) K

Gui, X.[Xia], Tang, Z.[ZhiGang], Fei, W.[Weiyang]
J. Chem. Eng. Data 2011, 56, 5, 2420-2429
ABSTRACT
The constant-volume method is used to determine the solubility of CO2 in methanol, ethanol, n-propanol, n-butanol, n-propanol, ethylene glycol, propylene glycol, acetone, 2-butanone, ethylene glycol monomethyl ether, and ethylene glycol monoethyl ether under the pressure of 6 MPa and the temperature variations from (288.15 to 318.15) K in this paper. It is found by contrast that ketones have a greater ability to dissolve CO2 than alcohols, ethers, and glycols, which also indicate that both the carbonyl group and the ether bond in solvents can promote the CO2 absorption, but hydroxyl group will inhibit the CO2 absorption.
Compounds
# Formula Name
1 CH4O methanol
2 CO2 carbon dioxide
3 C2H6O ethanol
4 C3H8O propan-1-ol
5 C4H10O butan-1-ol
6 C5H12O pentan-1-ol
7 C2H6O2 1,2-ethanediol
8 C3H8O2 1,2-propanediol
9 C3H6O acetone
10 C4H8O butanone
11 C3H8O2 2-methoxyethan-1-ol
12 C4H10O2 2-ethoxyethan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 67
  • POMD
  • 3
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 70
  • POMD
  • 4
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 65
  • POMD
  • 5
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 64
  • POMD
  • 6
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 59
  • POMD
  • 7
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 52
  • POMD
  • 8
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 54
  • POMD
  • 9
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 51
  • POMD
  • 10
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 49
  • POMD
  • 11
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 46
  • POMD
  • 12
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Liquid
  • Gas
  • Material Balance
  • 47