Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Gas Solubility in Binary Liquid Mixtures: Carbon Dioxide in Cyclohexane + Cyclohexanone

Merker, T.[Thorsten], Franke, N. W., Glaser, R.[Roger], Schleid, T.[Thomas], Hasse, H.[Hans]
J. Chem. Eng. Data 2011, 56, 5, 2477-2481
ABSTRACT
Experimental results are presented for the pressure above liquid mixtures of carbon dioxide and cyclohexane + cyclohexanone. The experiments were performed at a preset temperature and liquid phase composition by means of a precise high-pressure view-cell technique based on the synthetic method. The studied temperatures are: (313, 353, and 392) K. The maximum pressure was about 5.5 MPa. The gas free mole fractions of cyclohexanone are: 0, 0.3, 0.6, 0.8, and 1. From the data, Henry's law constants of carbon dioxide in the studied liquid mixtures and the pure components are calculated.
Compounds
# Formula Name
1 C6H12 cyclohexane
2 C6H10O cyclohexanone
3 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Pressure Transducer
  • 20
  • POMD
  • 2
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Pressure Transducer
  • 23
  • POMD
  • 2
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Pressure Transducer
  • 102