Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Pressures of Several Commercially Used Alkanolamines

Klepacova, K.[Katarina], Huttenhuis, P. J. G.[Patrick J.G.], Derks, P. W. J.[Peter W. J.], Versteeg, G. F.[Geert F.]
J. Chem. Eng. Data 2011, 56, 5, 2242-2248
ABSTRACT
For the design of acid gas treating processes, vapor-liquid equilibrium (VLE) data must be available of the solvents to be applied. In this study the vapor pressures of seven frequently industrially used alkanolamines (diethanolamine, N-methylethanolamine, N,N-dimethylethanolamine, N,N-diethylethanolamine, diisopropanol-amine, 2-(2-aminoethoxy)ethanol, 2-amino-2-methyl-1-propanol) were measured in an ebulliometer. The VLE experiments were carried out at presssures between (1 and 400) kPa and at a maximum temperature of 453 K. The experimental data can be used to improve the thermodynamic models in gas treating processes and to determine the amine losses in the absorber and desorber.
Compounds
# Formula Name
1 H2O water
2 C2H7NO 2-aminoethan-1-ol
3 C4H11NO2 diethanolamine
4 C3H9NO 2-(methylamino)ethanol
5 C4H11NO 2-(N,N-dimethylamino)ethanol
6 C6H15NO (diethylamino)ethanol
7 C6H15NO2 N-(2-hydroxypropyl)-2-hydroxy-1-propanamine
8 C4H11NO2 2-(2-aminoethoxy)ethanol
9 C4H11NO 2-amino-2-methylpropan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32
  • 7
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:32
  • 7
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 5
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 16
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 15
  • POMD
  • 6
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 13
  • POMD
  • 7
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 19
  • POMD
  • 8
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 9
  • POMD
  • 9
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:16
  • 15