Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physical Properties of Aqueous Solutions of Piperazine and (2-Amino-2-methyl-1-propanol + Piperazine) from (298.15 to 333.15) K

Murshid, G.[Ghulam], Shariff, A. M.[Azmi Mohd], Keong, L. K.[Lau Kok], Bustam, M. A.[Mohammad Azmi]
J. Chem. Eng. Data 2011, 56, 5, 2660-2663
ABSTRACT
The density (?), viscosity (?), surface tension (s), and refractive index (nD) of aqueous solutions of piperazine and aqueous blends of 2-amino-2-methyl-1-propanol (AMP) with piperazine were experimentally measured for a wide range of temperature (298.15 to 333.15) K. The physical properties were measured for piperazine mass fractions (1.74, 3.45, 6.88, and 10.35) and for aqueous blends of (AMP + PZ) with mass fractions {100 (w1/w2) = (28.26/1.74), (26.55/3.45), (23.12/6.88), (19.65/10.35)}. The concentrations for aqueous solutions of (AMP + PZ) were kept higher due to the growing interest in use of concentrated amines in gas processing. All of the measured physical property values were correlated as a function of temperature.
Compounds
# Formula Name
1 C4H10N2 piperazine
2 C4H11NO 2-amino-2-methylpropan-1-ol
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Gas
  • Pendant drop shape
  • 20
  • POMD
  • 1
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 32
  • POMD
  • 1
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • ABBE:UFactor:4
  • 20
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 32
  • POMD
  • 1
  • 2
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Gas
  • Pendant drop shape
  • 20
  • POMD
  • 1
  • 2
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 32
  • POMD
  • 1
  • 2
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • ABBE:UFactor:4
  • 20
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:8
  • 32