Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Phase Equilibria in Binary Mixtures of Propane and Phenanthrene: Experimental Data and Modeling with the GC-EoS

Breure, B.[Bianca], Straver, E. J. M.[Eugene J. M.], Florusse, L. J.[Louw J.], Rijkers, M. P. W. M.[Marijn P. W. M.], Economou, I. G.[Ioannis G.], Vargas, F. M.[Francisco M.], Peters, C. J.[Cor J.]
J. Chem. Eng. Data 2011, 56, 4, 1407-1413
ABSTRACT
In this paper experimental data are presented for the binary system propane + phenanthrene. Experimental measurements have been performed for various two-phase and three-phase equilibria, including equilibria in the presence of solid phenanthrene. Based on the course of the various three-phase equilibria, an estimation could be made for the location of the quadruple point solid phenanthrene-liquid-liquid-vapor (SL1L2G). Experimental work was performed for the temperature range 337 less than T/K less than 434 and pressures up to 22 MPa. Besides phase equilibrium data also liquid phenanthrene volume measurements are presented for temperatures between (377 and 425) K and pressure varying between (2 and 10) MPa. The experimental phase behavior data were compared to predictions made with the group contribution equation of state, resulting generally in a good agreement.
Compounds
# Formula Name
1 C14H10 phenanthrene
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar volume, m3/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 35
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal - 1
  • Temperature, K; Crystal - 1
  • Crystal - 1
  • Liquid mixture 2
  • Gas
  • Calletet apparatus
  • 28
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid mixture 2
  • Liquid mixture 1
  • Calletet apparatus
  • 14
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal - 1
  • Temperature, K; Gas
  • Crystal - 1
  • Gas
  • Liquid mixture 1
  • Calletet apparatus
  • 12
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal - 1
  • Temperature, K; Crystal - 1
  • Crystal - 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Calletet apparatus
  • 5
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid mixture 2
  • Mole fraction - 1; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Cailletet Apparatus
  • 54
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid mixture 2
  • Mole fraction - 1; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Gas
  • Cailletet Apparatus
  • 80
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Liquid mixture 1
  • Crystal - 1
  • Cailletet Apparatus
  • 5
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid mixture 2
  • Mole fraction - 1; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Crystal - 1
  • Cailletet Apparatus
  • 48
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Cailletet Apparatus
  • 60