Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

An Absolute Viscometer for Liquids: Measurement of the Viscosity of Water at T = 298.15 K and p = 0.1 MPa

Goodwin, A. R. H.[Anthony R. H.], Marsh, K. M.[Kenneth M.]
J. Chem. Eng. Data 2011, 56, 1, 167-170
ABSTRACT
A vibrating-wire viscometer has been formed from cold-drawn centerless-ground tungsten wire of a nominal radius of 0.15 mm. The working equations for the vibrating-wire viscometer require values of the wire radius and internal damping. The radius of the wire was determined by contact micrometry combined with laser interferometry while the internal damping was obtained from measurements in vacuum. With these values, the vibrating-wire instrument provides an absolute measure of the viscosity of liquids. The apparatus has been used to measure the viscosity of water at a temperature of 293.15 K and a pressure of 101.325 kPa. The result obtained differs by less than 0.03 % from the International Organization for Standardization (ISO) recommendation (ISO/TR 3666, 1998) for the viscosity of water. The relative expanded (k = 2) uncertainty of the viscosity obtained from the vibrating-wire viscometer is +- 0.9 %, that is, 3.6 times greater than the relative uncertainty of the ISO recommendation. This work illustrates, for the first time, that a vibrating wire can be operated as an absolute viscometer for liquids.
Compounds
# Formula Name
1 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating wire viscometry
  • 3