ABSTRACT

The solubility of (a,Z)-2-amino-a-(methoxyimino)-4-thiazoleethanethioic acid S-2-benzothiazolyl ester in dichloromethane, acetonitrile, tetrahydrofuran, 1,2-dichloroethane, acetone, and binary mixtures of tetrahydrofuran + dichloromethane or 1,2-dichloroethane was measured using a laser monitoring observation technique. The temperature dependence of the solubility of the solute was estimated using the modified Apelblat equation based on the data presented in this work. The calculated solubilities show good agreement with the experimental values.

Compounds

#	Formula	Name
1	C13H10N4O2S3	(.alpha.Z)-2-amino-.alpha.-(methoxyimino)-4-thiazoleethanethioic acid S-2-benzothiazolyl ester
2	CH2Cl2	dichloromethane
3	C4H8O	tetrahydrofuran
4	C2H3N	acetonitrile
5	C2H4Cl2	1,2-dichloroethane
6	C3H6O	acetone

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	6
POMD	3 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	6
POMD	4 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	6
POMD	5 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	6
POMD	6 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	6
POMD	2 3 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	36
POMD	5 3 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid Solvent: Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Laser monitoring observation technique	42

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of (a,Z)-2-Amino-a-(methoxyimino)-4-thiazoleethanethioic Acid S-2-Benzothiazolyl Ester in Different Pure Solvents and Binary Mixtures of Tetrahydrofuran + Dichloromethane or 1,2-Dichloroethane

Liu, J.[Jisheng], Wang, S.[Shui], Zhou, Z.[Zhimao], Qu, Y.[Yixin], Zhang, M.[Meijuan]

ABSTRACT