Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation of Solubilities of Cefpirome Sulfate in Aqueous Alcohol Solution between (278.15 and 308.15) K

Li, Y.[Yu], Wang, F. -A.[Fu-An], Ren, B.-z.[Bao-zeng]
J. Chem. Eng. Data 2010, 55, 11, 5375-5381
ABSTRACT
The solubilities of cefpirome sulfate in water + (methanol, ethanol, 1-propanol, or 2-propanol) solvent mixtures have been measured using a dynamic method at temperature ranging from (278.15 to 318.15) K at atmospheric pressure. A solubility equation was proposed and verified by experimental results. The dissolution enthalpy and dissolution entropy have been calculated from the solubility data. The interactions between solute and solvent were discussed.
Compounds
# Formula Name
1 C22H24N6O9S3 cefpirome sulfate
2 H2O water
3 CH4O methanol
4 C2H6O ethanol
5 C3H8O propan-1-ol
6 C3H8O propan-2-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Observation
  • 7
  • POMD
  • 3
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Observation
  • 63
  • POMD
  • 4
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Observation
  • 42
  • POMD
  • 5
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 5; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Observation
  • 42
  • POMD
  • 6
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Solvent: Mole fraction - 6; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Observation
  • 42