Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Water Activity Measurement for Alanine + Dipotassium Oxalate + Water and the Corresponding Binary Solutions at Different Temperatures

Zafarani-Moattar, M. T.[Mohammed Taghi], Davoodi, S.[Sepideh]
J. Chem. Eng. Data 2010, 55, 11, 5219-5224
ABSTRACT
Water activity measurements by the isopiestic method have been carried out on the aqueous ternary system of l-alanine + dipotassium oxalate and the aqueous binary system of dipotassium oxalate over a range of temperatures at atmospheric pressure. From these measurements, values of the vapor pressure of solutions were determined. The experimental vapor-liquid equilibria data for the binary system were correlated with the Pitzer equation. The agreement between the correlations and the experimental data is good. A model based on the Pitzer formalism has been employed to correlate the experimental osmotic coefficient data for the ternary system, and the results show that this model can be satisfactorily used.
Compounds
# Formula Name
1 C3H7NO2 (S)-2-aminopropanoic acid
2 C2H2K2O5 potassium oxalate monohydrate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 3
  • Osmotic coefficient ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Liquid
  • Gas
  • ISOPIE
  • 58
  • POMD
  • 1
  • 2
  • 3
  • (Relative) activity - 3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Liquid
  • Gas
  • Isopiestic method
  • 120
  • POMD
  • 1
  • 2
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Liquid
  • Gas
  • Isopiestic method
  • 120