Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Density and surface tension of the air- and water-stable hydrophobic ionic liquids N-alkylpyridinium bis(trifluoromethylsulfonyl)imide ([Cnpy][NTf2], n = 2, 4, 5) were measured in the temperature range T = (283.15 to 338.15) K. The melting temperatures of the samples were determined by differential scanning calorimetry (DSC). Decomposition temperatures are higher than 600 K as determined by thermogravimetric analysis (TG).

Compounds

#	Formula	Name
1	C9H10F6N2O4S2	1-ethylpyridinium bis[(trifluoromethyl)sulfonyl]imide
2	C11H14F6N2O4S2	1-butylpyridinium bis[(trifluoromethyl)sulfonyl]imide
3	C12H16F6N2O4S2	1-pentylpyridinium bis(trifluoromethylsulfonyl)amide

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Molar enthalpy of transition or fusion, kJ/mol ; Crystal 1			Crystal 1 Liquid Air at 1 atmosphere	DSC:UFactor:4	1
POMD	1	Triple point temperature, K ; Glass			Glass Liquid Air at 1 atmosphere	DTA	1
POMD	1	Triple point temperature, K ; Crystal 2			Crystal 2 Crystal 1 Air at 1 atmosphere	DTA	1
POMD	1	Normal melting temperature, K ; Crystal 1			Crystal 1 Liquid Air at 1 atmosphere	DTA	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Buoyancy - hydrostatic balance with magnetic suspension - one sinker	11
POMD	1	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid		Liquid Air at 1 atmosphere	Ring tensiometer	11
POMD	2	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC:UFactor:4	1
POMD	2	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DTA	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Buoyancy - hydrostatic balance with magnetic suspension - one sinker	9
POMD	2	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid		Liquid Air at 1 atmosphere	Ring tensiometer	8
POMD	3	Molar enthalpy of transition or fusion, kJ/mol ; Crystal			Crystal Liquid Air at 1 atmosphere	DSC:UFactor:4	1
POMD	3	Triple point temperature, K ; Glass			Glass Liquid Air at 1 atmosphere	DTA	1
POMD	3	Normal melting temperature, K ; Crystal			Crystal Liquid Air at 1 atmosphere	DTA	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Buoyancy - hydrostatic balance with magnetic suspension - one sinker	12
POMD	3	Surface tension liquid-gas, N/m ; Liquid	Temperature, K; Liquid		Liquid Air at 1 atmosphere	Ring tensiometer	12

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density and Surface Tension of Ionic Liquids [Cnpy][NTf2] (n = 2, 4, 5)

Liu, Q.-S.[Qing-Shan], Yang, M.[Miao], Yan, P.-F.[Pei-Fang], Liu, X.-M.[Xiu-Mei], Tan, Z.-C.[Zhi-Cheng], Welz-Biermann, U.[Urs]

ABSTRACT