ABSTRACT

Densities, speeds of sound, and refractive indices of binary mixtures of decan-1-ol with 2-methylphenol (o-cresol), 3-methylphenol (m-cresol), 4-methylphenol (p-cresol), and methyl phenyl ether (anisole) were measured over the entire range of composition from T = (298.15 to 308.15) K and at a pressure of 0.1 MPa. The experimental values of densities were used to calculate the excess molar volumes of the binary liquid mixtures. Excess molar volumes have been fitted to the Redlich-Kister polynomial equation to derive the binary coefficients and the standard errors between the experimental and the calculated quantities. The excess molar volumes are negative over the entire composition range for the binary mixtures of decan-1-ol with m-cresol and p-cresol and give an s-shaped curve with o-cresol at the high mole fraction region of o-cresol. For the binary mixtures of decan-1-ol with anisole, the excess molar volume is positive.

Compounds

#	Formula	Name
1	C10H22O	decan-1-ol
2	C7H8O	2-methylphenol
3	C7H8O	3-methylphenol
4	C7H8O	4-methylphenol
5	C7H8O	anisole

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	4
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	3
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	3
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	3
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	3
POMD	5 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	48
POMD	5 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	48
POMD	5 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	48
POMD	2 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	48
POMD	2 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	48
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	48
POMD	3 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	48
POMD	3 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	48
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	48
POMD	4 1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	48
POMD	4 1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Sing-around technique in a fixed-path interferometer	48
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	48

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities, Speeds of Sound, and Refractive Indices of Binary Mixtures of Decan-1-ol with Anisole, o-Cresol, m-Cresol, and p-Cresol at T = (298.15, 303.15, and 308.15) K

Bhatia, S. C.[Subhash C.], Rani, R.[Ruman], Bhatia, R.[Rachna]

ABSTRACT