Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of CO2 in Propanone, 1-Ethyl-3-methylimidazolium Tetrafluoroborate, and Their Mixtures

Lei, Z.[Zhigang], Yuan, J.[Juan], Zhu, J.[Jiqin]
J. Chem. Eng. Data 2010, 55, 10, 4190-4194
ABSTRACT
Solubility data of carbon dioxide (CO2) (1) in propanone (2), 1-ethyl-3-methylimidazolium ([EMIM]+[BF4]-) (3), and their mixtures (w3 = 0.10, 0.20, and 0.50) at temperatures (298.2 and 313.2) K and pressures up to 8.0 MPa were measured by means of a high-pressure view-cell technique. Henry s law was applied to correlate the experimental data, and it was found that the magnitude of Henry s constants for propanone (w3 = 0.0), [EMIM]+[BF4]- (w3 = 1.0), and their mixtures follows the order of w3 = 0.0 less than w3 = 0.10 less than w3 = 0.20 less than w3 = 0.50 less than w3 = 1.0 at a given temperature. The mixtures of propanone and [EMIM]+[BF4]- may be used as promising solvents for capturing CO2 since they combine the advantages of organic solvents and ionic liquids.
Compounds
# Formula Name
1 C3H6O acetone
2 CO2 carbon dioxide
3 C6H11BF4N2 1-ethyl-3-methylimidazolium tetrafluoroborate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Manometric method
  • 23
  • POMD
  • 1
  • 2
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 23
  • POMD
  • 2
  • 3
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 17
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 36
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 2 ; Gas
  • Temperature, K; Gas
  • Mole fraction - 2; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 36