ABSTRACT

The solubilities of decabromodiphenyl ether (DeBDE) in propanone, ethyl acetate, 1-methyl-4-(1-methylethenyl)cyclohexene, methylbenzene, and tetrahydrofuran were measured in the temperature range of (283.0 to 323.0) K by high-performance liquid chromatography (HPLC). The modified Apelblat equation was used to correlate the relationship between solubility and temperature. The correlated data showed a good agreement with the experimental results. These data of solubility can be used in the optimized separation of decabromodiphenyl ether.

Compounds

#	Formula	Name
1	C12Br10O	6,6'-oxybis(1,2,3,4,5-pentabromobenzene)
2	C3H6O	acetone
3	C4H8O2	ethyl acetate
4	C10H16	1-methyl-4-(1-methylethenyl)cyclohexene
5	C7H8	toluene
6	C4H8O	tetrahydrofuran

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Chromatography	5
POMD	3 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Chromatography	5
POMD	4 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Chromatography	5
POMD	5 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Chromatography	5
POMD	6 1	Mole fraction - 1 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid Crystal - 1	Chromatography	5

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Decabromodiphenyl Ether in Different Solvents at (283.0 to 323.0) K

Guan, G.[Guoqiang], Chen, L.[Lieqiang], Peng, S.[Shaohong]

ABSTRACT