Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physicochemical Properties of an Ionic Liquid [C2mim][B(CN)4]

Tong, J.[Jing], Liu, Q.-S.[Qing-Shan], Kong, Y.-X.[Yu-Xia], Fang, D.-W.[Da-Wei], Welz-Biermann, U.[Urs], Yang, J. -Z.[Jia-Zhen]
J. Chem. Eng. Data 2010, 55, 9, 3693-3696
ABSTRACT
The density and surface tension of the ionic liquid (IL) [C2mim][B(CN)4] (1-ethyl-3-methylimidazolium tetracyanoborate) were measured in a temperature range from (283.15 to 338.15) K. In terms of Glasser s semiempirical relation of ILs, the standard molar entropy and the lattice energy of the homologous series of ILs [Cnmim][B(CN)4] were estimated, respectively. Using Kabo s method and Rebelo s method, the molar enthalpy of vaporization of [C2mim][B(CN)4], ?lgHm0 (298 K), at 298 K, and ?lgHm0 (Tb), at hypothetical normal boiling point, Tb = 680 K, was estimated, respectively. According to the interstice model, the thermal expansion coefficient of [C2mim][B(CN)4], a = 4.77*10-4 K-1, was estimated and was in good agreement with experimental value.
Compounds
# Formula Name
1 C10H11BN6 1-ethyl-3-methylimidazolium tetracyanoborate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Maximal bubble pressure
  • 12
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 12