Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Data and Correlation of Surface Tensions of the Binary and Ternary Systems of Water + Acetonitrile + 2-Propanol at 298.15 K and Atmospheric Pressure

Rafati, A. A.[Amir Abbas], Bagheri, A.[Ahmad], Najafi, M.[Mojgan]
J. Chem. Eng. Data 2010, 55, 9, 4039-4043
ABSTRACT
This paper reports the results of a new experimental study of surface tension for the ternary mixtures of water/acetonitrile/2-propanol. Correlating the excess surface tension of the above-mentioned binary and ternary systems was performed with empirical and thermodynamic based models. The methods of Pando et al. and Ku et al. were used to correlate the ternary surface tension data. The ternary surface tension data were well-correlated using pair additivity and rational functions as the ternary term. The results provide information on the molecular interactions between the unlike molecules that exist at the surface and the bulk.
Compounds
# Formula Name
1 C2H3N acetonitrile
2 C3H8O propan-2-ol
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 1
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 1
  • POMD
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 1
  • POMD
  • 1
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 12
  • POMD
  • 2
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 11
  • POMD
  • 2
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 11
  • POMD
  • 2
  • 1
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 3; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 66