Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

P-V-T Behavior of 2,3,3,3-Tetrafluoroprop-1-ene (HFO-1234yf) in the Vapor Phase from (243 to 373) K

Nicola, C. D.[Cristiano Di], Nicola, G. D.[Giovanni Di], Pacetti, M.[Marco], Polonara, F.[Fabio], Santori, G.[Giulio]
J. Chem. Eng. Data 2010, 55, 9, 3302-3306
ABSTRACT
The P-V-T properties of 2,3,3,3-tetrafluoroprop-1-ene (CF3CF-CH2, HFO-1234yf), an environmentally friendly refrigerant, were measured using a constant volume apparatus. Measurements were carried out at temperatures from (243 to 373) K and at pressures from (84 to 3716) kPa. A total of 136 experimental points, taken along 12 isochores, were obtained. Our experimental results were compared with a preliminary equation of state. The measurements were also regressed to the Martin-Hou equation of state. No other data on this fluid were found in the literature for the superheated region.
Compounds
# Formula Name
1 C3H2F4 2,3,3,3-tetrafluoro-1-propene
2 C2H2F4 1,1,1,2-tetrafluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar volume, m3/mol ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 136
  • POMD
  • 2
  • Molar volume, m3/mol ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • ISOCHOR
  • 24