Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibrium for Carbon Dioxide + Isopropyl, Isobutyl, and Isoamyl Acetates

Kwon, C.[Cheong] Hoon, Seo, M. D.[Myung Do], Kim, S. W.[Seung Wook], Lee, C. S.[Chul Soo], Kang, j. W.[jeong Won]
J. Chem. Eng. Data 2007, 52, 3, 727-730
ABSTRACT
Vapor-liquid equilibrium of three acetates (isopropyl, isobutyl, and isoamyl acetate) + carbon dioxide were measured using a circulating-type equilibrium cell at temperature ranging from (313.2 to 333.2) K and pressure up to 10 MPa. The measured experimental data were correlated by the Peng-Robinson with conventional mixing rule and nonrandom lattice fluid with hydrogen bonding equations of state with a single binary interaction parameter.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 C5H10O2 1-methylethyl ethanoate
3 C6H12O2 2-methylpropyl ethanoate
4 C7H14O2 3-methylbutyl ethanoate
5 C7H8 toluene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 5
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 10
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 10
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 30
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 30
  • POMD
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 30
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 30
  • POMD
  • 4
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 30
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Chromatography
  • 30