Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solid-Liquid Equilibria for the CO2 + R125 and N2O + R125 Systems: A New Apparatus

Di Nicola, G.[Giovanni], Giuliani, G.[Giuliano], Polonara, F.[Fabio], Stryjek, R.[Roman]
J. Chem. Eng. Data 2006, 51, 6, 2209-2214
ABSTRACT
A new experimental setup was built for the estimation of the solid-liquid equilibria of alternative refrigerant systems. The system s behavior was measured down to temperatures of 143 K using two binaries (i.e., carbon dioxide + 1,1,1,2,2-pentafluoroethane (CO2 + R125) and nitrous oxide + 1,1,1,2,2-pentafluoroethane (N2O + R125)). The setup enabled us to record not only temperature and composition data but also pressure data. The triple points of the pure fluids contained in the mixture were measured to check the reliability of the new apparatus, revealing a good consistency with the literature. The results obtained for the mixtures were interpreted by means of the Schroder equation.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 N2O nitrous oxide
3 C2HF5 pentafluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal
  • Crystal
  • Liquid
  • Gas
  • heating/cooling curve
  • 1
  • POMD
  • 1
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • Heating/Cooling curves
  • 1
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Crystal
  • Crystal
  • Liquid
  • Gas
  • heating/cooling curve
  • 1
  • POMD
  • 2
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • Heating/Cooling curves
  • 1
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Crystal
  • Crystal
  • Liquid
  • Gas
  • heating/cooling curve
  • 1
  • POMD
  • 3
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • Heating/Cooling curves
  • 1
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Crystal - 3
  • Gas
  • time/temp cooling curve
  • 6
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Crystal - 1
  • Gas
  • time/temp cooling curve
  • 14
  • POMD
  • 1
  • 3
  • Triple point temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Crystal - 3
  • Gas
  • time/temp cooling curves
  • 6
  • POMD
  • 1
  • 3
  • Triple point temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Crystal - 1
  • Gas
  • time/temp cooling curves
  • 14
  • POMD
  • 3
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 3
  • Gas
  • time/temp cooling curve
  • 8
  • POMD
  • 3
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 2
  • Gas
  • time/temp cooling curve
  • 10
  • POMD
  • 3
  • 2
  • Triple point temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 3
  • Gas
  • time/temp cooling curves
  • 8
  • POMD
  • 3
  • 2
  • Triple point temperature, K ; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Crystal - 2
  • Gas
  • time/temp cooling curves
  • 10