ABSTRACT

Densities and viscosities at (298.15, 308.15, and 318.15) K are presented as a function of mixture composition for the binary mixtures of propylene glycol monomethyl ether with methacrylic acid, benzyl methacrylate, and 2-hydroxyethyl methacrylate. From the experimental data, the excess molar volumes and viscosity deviations have been calculated. These results have been correlated with the Redlich-Kister type polynomial to derive the coefficients and standard deviation. McAllister s three-body and four-body interaction models were also used to correlate the kinematic viscosities. These model s parameters were treated to be temperature-dependent.

Compounds

#	Formula	Name
1	C4H6O2	2-methyl-2-propenoic acid
2	C11H12O2	benzyl methacrylate
3	C6H10O3	2-hydroxyethyl 2-methyl-2-propenoate
4	C4H10O2	1-methoxy-2-propanol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	3
POMD	1 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	1 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33
POMD	4 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	4 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33
POMD	4 3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	33
POMD	4 3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Pycnometric method	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Excess Molar Volumes and Viscosities for Binary Mixtures of Propylene Glycol Monomethyl Ether with Methacrylic Acid, Benzyl Methacrylate, and 2-Hydroxyethyl Methacrylate at (298.15, 308.15, and 318.15) K

Chen, J. -T.[Jui-Tang], Shiah, I. M.[I-Min], Chu, H.-P.[Hsiao-Pei]

ABSTRACT