ABSTRACT

The viscosities, densities, and speeds of sound of binary mixtures of anisole with benzene, toluene, o-xylene, m-xylene, p-xylene, and mesitylene over the entire range of mole fraction at temperatures (288.15, 293.15, 298.15, and 303.15) K and atmospheric pressure have been measured. Excess compressibility and deviations in viscosity have been calculated and fitted to the Redlich-Kister polynomial relation to estimate the binary coefficients and standard errors. The deviations in viscosities and excess compressibilities are negative for all binary systems. The speeds of sound have been analyzed in terms of collision factor theory and free length theory. The viscosity data were correlated with equations of Grunberg and Nissan, Tamura and Kurata, Heric and Brewer, and McAllister.

Compounds

#	Formula	Name
1	C6H6	benzene
2	C7H8	toluene
3	C8H10	1,2-dimethylbenzene
4	C8H10	1,3-dimethylbenzene
5	C8H10	1,4-dimethylbenzene
6	C9H12	1,3,5-trimethylbenzene
7	C7H8O	anisole

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	OTHER::sMethod:Anton Paar Stabinger viscometer	4
POMD	1	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:8	4
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	4
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	OTHER::sMethod:Anton Paar Stabinger viscometer	4
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:8	4
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	4
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	OTHER::sMethod:Anton Paar Stabinger viscometer	4
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:8	4
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	4
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	OTHER::sMethod:Anton Paar Stabinger viscometer	4
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:8	4
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	4
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	OTHER::sMethod:Anton Paar Stabinger viscometer	4
POMD	5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:8	4
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	4
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	OTHER::sMethod:Anton Paar Stabinger viscometer	4
POMD	6	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT::UFactor:8	4
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB::UFactor:4	4
POMD	7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	4
POMD	7	Speed of sound, m/s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	5
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	12
POMD	7 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	44
POMD	7 2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	44
POMD	7 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	44
POMD	3 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	44
POMD	3 7	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	44
POMD	3 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	44
POMD	7 4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	44
POMD	7 4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	44
POMD	7 4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	44
POMD	7 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	44
POMD	7 5	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	44
POMD	7 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	44
POMD	7 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	44
POMD	7 6	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	44
POMD	7 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	44
POMD	1 7	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Anton Paar Stabinger viscometer	44
POMD	1 7	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	44
POMD	1 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:4	44

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosities, Densities, and Speeds of Sound of Binary Mixtures of Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Mesitylene with Anisole at (288.15, 293.15, 298.15, and 303.15) K

Al-Kandary, J. A.[Jasem A.], Al-Jimaz, A. S.[Adel S.], Abdul-Latif, A.-H. M.[Abdul-Haq M.]

ABSTRACT