Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement and Correlation of Isothermal Vapor-Liquid Equilibrium Data for the System Acetonitrile + Water + Tetrapropylammonium Bromide

Kurzin, A. V.[Alexander V.], Evdokimov, A. N.[Andrey N.], Antipina, V. B.[Victorija B.], Pavlova, O. S.[Olesja S.]
J. Chem. Eng. Data 2006, 51, 4, 1361-1363
ABSTRACT
Isothermal vapor-liquid equilibrium data for the system acetonitrile + water + tetrapropylammonium bromide at four constant salt molalities [(0.200, 0.400, 0.800, and 1.000) mol*kg-1] have been measured with the help of headspace gas chromatography at (298.15 and 323.15) K. The experimental data were correlated using two different electrolyte models: an electrolyte nonrandom two-liquid model and an electrolyte universal quasi-chemical functional-group activity coefficients model. Mean absolute deviations of vapor phase compositions for these models were 0.006 and 0.007, respectively.
Compounds
# Formula Name
1 C2H3N acetonitrile
2 H2O water
3 C12H28BrN tetrapropylammonium bromide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • 2
  • Mole fraction - 1 ; Gas
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Solvent: Mole fraction - 1; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 80