Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities and Viscosities for the Ternary Systems of Methyl tert-Butyl Ether + Methanol + Benzene and Methyl tert-Butyl Ether + Methanol + Toluene and Their Sub-binary Systems at 298.15 K

Han, K. J.[Kyu-Jin], Oh, J. -H.[Jong-Hyeog], Park, S.-J.[So-Jin]
J. Chem. Eng. Data 2006, 51, 4, 1339-1344
ABSTRACT
Excess molar volumes (V E) and viscosity deviations (centse) at 298.15 K are reported for the five binary systems of methyl tert-butyl ether (MTBE) + methanol, methanol + benzene, MTBE + benzene, methanol + toluene, and MTBE + toluene and also for the ternary systems of MTBE + methanol + benzene and MTBE + methanol + toluene. The experimental V E and centse data were correlated with Redlich-Kister and Cibulka equation for the binary systems and the ternary system, respectively. The measured binary V E and centse data were compared with the literature values, and the ternary data were compared with the calculated values using the binary contribution models of Tsao-Smith, Kohler, Rastogi, and Radojkovic.
Compounds
# Formula Name
1 C5H12O 2-methoxy-2-methylpropane
2 CH4O methanol
3 C6H6 benzene
4 C7H8 toluene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 1
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 1
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 11
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 11
  • POMD
  • 2
  • 3
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 11
  • POMD
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 11
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:4
  • 11
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 11
  • POMD
  • 2
  • 4
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 11
  • POMD
  • 2
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 11
  • POMD
  • 4
  • 1
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 11
  • POMD
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 11
  • POMD
  • 2
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 64
  • POMD
  • 2
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 64
  • POMD
  • 2
  • 4
  • 1
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • CAPTUB:UFactor:2
  • 66
  • POMD
  • 2
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 66