Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Distribution of Butyric Acid between Water and Several Solvents

Bilgin, M.[Mehmet], Kirbaslar, S. I., Ozcan, O.[Onder], Dramur, U.[Umur]
J. Chem. Eng. Data 2006, 51, 5, 1546-1550
ABSTRACT
Distribution of butyric acid between water and trioctylamine dissolved in 17 solvents (isoamyl alcohol, 1-nonanol, 1-decanol, 1-dodecanol, oleyl alcohol, methyl ethyl ketone, isopropyl methyl ketone, isobutyl methyl ketone, 4-heptanone, ethyl acetate, cyclohexyl acetate, dimethyl phthalate, dibutyl phthalate, tert-butyl methyl ether, kerosene, n-hexane, toluene) and 4 vegetable oils (haselnut, corn, soybean, olive) have been studied at T ) 298.15 K. The highest distribution coefficient for butyric acid is shown by trioctylamine dissolved in isoamyl alcohol. As the molar mass of the alcohol increases, the value of the distribution coefficient decreases. In the amine extraction, it was observed that the use of trioctylamine dissolved in alcohol increased the distribution coefficient between 6 and 7 times; dissolving in ketones increased the distribution between 3 and 5 times; dissolving in esters increased it 4 to 9 times; dissolving in tert-butyl methyl ether increased it 2.3 times; dissolving in hydrocarbons increased it 10 to 18 times; and dissolving in vegetable oils increased it 12.5 times, all as compared to use of the pure solvents as extractant.
Compounds
# Formula Name
1 H2O water
2 C4H8O2 butanoic acid
3 C24H51N trioctylamine
4 C5H12O 3-methylbutan-1-ol
5 C9H20O nonan-1-ol
6 C10H22O decan-1-ol
7 C12H26O dodecan-1-ol
8 C18H36O (Z)-9-octadecen-1-ol
9 C4H8O butanone
10 C5H10O 3-methyl-2-butanone
11 C6H12O 4-methylpentan-2-one
12 C7H14O 4-heptanone
13 C4H8O2 ethyl acetate
14 C8H14O2 cyclohexyl ethanoate
15 C10H10O4 dimethyl 1,2-benzenedicarboxylate
16 C16H22O4 dibutyl phthalate
17 C5H12O 2-methoxy-2-methylpropane
18 C6H14 hexane
19 C7H8 toluene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 5
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 6
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 8
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 8
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 9
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 9
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 10
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 10
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 11
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 11
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 12
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 12
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 13
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 13
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 14
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 14
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 15
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 15
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 16
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 16
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 17
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 17
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 18
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 18
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 19
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 19
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 2
  • 4
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 5
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 6
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 7
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 8
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 9
  • 2
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 10
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 11
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 12
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 13
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 14
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 15
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 16
  • 2
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 17
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 19
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1
  • POMD
  • 2
  • 18
  • 1
  • Amount concentration (molarity), mol/dm3 - 2 ; Liquid mixture 1
  • Amount concentration (molarity), mol/dm3 - 2; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • titration
  • 1