Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor-Liquid Equilibrium of Ferrocene in Some Organic Solvents Using Spectroscopic Methods

Siddiqi, M. A.[Mohammed Aslam], Atakan, B.[Burak]
J. Chem. Eng. Data 2006, 51, 3, 1092-1096
ABSTRACT
Isobaric vapor-liquid equilibrium (VLE) data were measured at p ) 1.01325 bar for the mixtures of ferrocene in ethanol, toluene, hexane, and 2,2,4-trimethylpentane (isooctane). A dynamical equilibrium apparatus has been used to establish the equilibrium between the phases. The spectrophotometric method has been used to measure the compositions of vapor and liquid phases. Ferrocene is only weakly soluble in these solvents. The experimental binary data were correlated with the NRTL and UNIQUAC models, and the parameters were determined.
Compounds
# Formula Name
1 C10H10Fe ferrocene
2 C2H6O ethanol
3 C7H8 toluene
4 C6H14 hexane
5 C8H18 2,2,4-trimethylpentane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 1
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 1
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 1
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 1
  • POMD
  • 2
  • 1
  • Boiling temperature at pressure P, K ; Gas
  • Mole fraction - 1; Gas
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • EBULLIO:UFactor:8
  • 11
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Mole fraction - 1; Gas
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • CHROM:UFactor:4
  • 11
  • POMD
  • 1
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 12
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 12
  • POMD
  • 1
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 11
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 11
  • POMD
  • 1
  • 5
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 11
  • POMD
  • 1
  • 5
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:4
  • 11