ABSTRACT

cess volumes (V E), ultrasonic sound velocities (u), and viscosities () have been measured for the binary mixtures of acetophenone with o-chlorotoluene, m-chlorotoluene, p-chlorotoluene, o-nitrotoluene, and m-nitrotoluene at 303.15 K. Excess volumes are positive over the entire composition range in all the binary mixtures. Furthermore, from the experimental sound velocity data isentropic compressibility (KS) and deviation in isentropic compressibility (KS) from ideal behavior was also computed at the same temperature, and these values are negative in all the binary mixtures. The viscosity data are analyzed on the basis of corresponding states approach. Deviation in viscosities are positive over the entire composition range. The measured data are explained on the basis of intermolecular interactions between unlike molecules.

Compounds

#	Formula	Name
1	C8H8O	acetophenone
2	C7H7Cl	2-chlorotoluene
3	C7H7Cl	3-chlorotoluene
4	C7H7Cl	4-chlorotoluene
5	C7H7NO2	2-nitrotoluene
6	C7H7NO2	3-nitrotoluene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB:UFactor:4	1
POMD	1	Speed of sound, m/s ; Liquid		Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	2
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:4	1
POMD	2	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	FPINT::UFactor:8	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:4	1
POMD	3	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	FPINT::UFactor:8	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:4	1
POMD	4	Speed of sound, m/s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	FPINT::UFactor:16	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:4	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	CAPTUB::UFactor:4	1
POMD	2 1	Viscosity, Pa*s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	12
POMD	2 1	Speed of sound, m/s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	12
POMD	2 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	1 3	Viscosity, Pa*s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	12
POMD	1 3	Speed of sound, m/s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	12
POMD	1 3	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	1 4	Viscosity, Pa*s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	12
POMD	1 4	Speed of sound, m/s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	FPINT:UFactor:16	12
POMD	1 4	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	5 1	Viscosity, Pa*s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	12
POMD	5 1	Speed of sound, m/s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	11
POMD	5 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	1 6	Viscosity, Pa*s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	CAPTUB:UFactor:4	12
POMD	1 6	Speed of sound, m/s ; Liquid	Volume fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	FPINT:UFactor:8	11
POMD	1 6	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Excess Volumes, Speeds of Sound, Isentropic Compressibilities, and Viscosities of Binary Mixtures of Acetophenone with Chlorotoluenes and Nitrotoluenes at 303.15 K

Syamala, V.[Vardhana], Venkateswarlu, P.[Ponneri], Kumar, K. S.[Kasibhatta Siva]

ABSTRACT