ABSTRACT

Densities and viscosities were measured for the binary mixtures of 1,4-dioxane and 1,3-dioxolane with butyl acetate, butyric acid, butylamine, and 2-butanone at 298.15 K over the entire composition range. From density and viscosity data, the values of excess molar volume (V E) and viscosity deviation (centse) have been determined. These results were fitted to Redlich-Kister type polynomial equations. The density and viscosity data have been analyzed in terms of some semiempirical viscosity models.

Compounds

#	Formula	Name
1	C3H6O2	1,3-dioxolane
2	C4H8O2	1,4-dioxane
3	C6H12O2	butyl ethanoate
4	C4H8O2	butanoic acid
5	C4H11N	1-butanamine
6	C4H8O	butanone

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	1	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	PYCNOM:UFactor:2	1
POMD	2	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	CAPTUB:UFactor:2	1
POMD	2	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	PYCNOM:UFactor:2	1
POMD	3	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	3	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	PYCNOM::UFactor:2	1
POMD	4	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	4	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	PYCNOM::UFactor:2	1
POMD	5	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	5	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	PYCNOM::UFactor:2	1
POMD	6	Viscosity, Pa*s ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	CAPTUB::UFactor:2	1
POMD	6	Mass density, kg/m3 ; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid		Liquid	PYCNOM::UFactor:2	1
POMD	6 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	6 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	4 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	4 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	3 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	3 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	5 1	Viscosity, Pa*s ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	5 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	6 2	Viscosity, Pa*s ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	6 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	4 2	Viscosity, Pa*s ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	4 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	3 2	Viscosity, Pa*s ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	3 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11
POMD	5 2	Viscosity, Pa*s ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	CAPTUB:UFactor:2	11
POMD	5 2	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	PYCNOM:UFactor:2	11

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Excess Molar Volumes and Viscosity Deviations of Binary Liquid Mixtures of 1,3-Dioxolane and 1,4-Dioxane with Butyl Acetate, Butyric Acid, Butylamine, and 2-Butanone at 298.15 K

Roy, M. N.[Mahendra Nath], Sinha, B.[Biswajit], Kumar Dakua, V.[Vikas]

ABSTRACT