Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental (P, V, T, x) Data for the Mixture Ethyl Nonafluorobutyl Ether + n-Hexane

Cendon, J.[Javier], Vijande, J., Legido, J. L.[Jose Luis], Pineiro, M. M.[Manuel M.]
J. Chem. Eng. Data 2006, 51, 2, 577-581
ABSTRACT
Experimental high-pressure density data for the binary mixture of methyl nonafluorobutyl ether + hexane were determined. The pressure range considered was 0.1 to 25 MPa, and densities were measured along three isotherms, at temperatures of (283.15, 298.15, and 313.15) K. An Anton Paar DMA 4500 vibrating-tube densimeter, connected to a high-pressure measuring cell, was used for density measurement. Experimental data for the mixture were fitted using a modified Tait equation. Excess molar volumes were as well calculated and correlated, using a modified Redlich-Kister equation, which includes a temperature- and pressure-dependent factor.
Compounds
# Formula Name
1 C6H14 hexane
2 C6H5F9O 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane
3 C6H5F9O nonafluoroisobutyl ethyl ether
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Solvent: Mole fraction - 2; Liquid
  • Liquid
  • VIBTUB:UFactor:2
  • 420