Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Thermodynamic Properties of Mixtures Containing Ionic Liquids. 8. Activity Coefficients at Infinite Dilution of Hydrocarbons, Alcohols, Esters, and Aldehydes in 1-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl) Imide Using Gas-Liquid Chromatography

Heintz, A.[Andreas], Verevkin, S. P.[Sergey P.], Ondo, D.[Daniel]
J. Chem. Eng. Data 2006, 51, 2, 434-437
ABSTRACT
Activity coefficients at infinite dilution of alkanes, alkenes, and alkylbenzenes as well as of the linear and branched C1-C6 alcohols, esters, and aldehydes in the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide have been determined by gas chromatography using the ionic liquids as stationary phase. The measurements were carried out at different temperatures between 301 K and 396 K. From the temperature dependence of the limiting activity coefficients, partial molar excess enthalpies at infinite dilution of the solutes in the ionic liquids have been derived.
Compounds
# Formula Name
1 C10H14 butylbenzene
2 C11H16 pentylbenzene
3 C3H6O propanal
4 C4H8O butanal
5 C5H10O pentanal
6 C6H12O hexanal
7 C7H14O heptanal
8 C8H16O octanal
9 C4H8O2 methyl propanoate
10 C5H10O2 methyl butanoate
11 C6H12O2 methyl pentanoate
12 C7H14O2 methyl hexanoate
13 C8H16O2 methyl heptanoate
14 C3H6O acetone
15 C2H3N acetonitrile
16 C4H8O2 1,4-dioxane
17 CHCl3 trichloromethane
18 C5H12 pentane
19 C6H14 hexane
20 C7H16 heptane
21 C8H18 octane
22 C9H20 nonane
23 C10H22 decane
24 C11H24 undecane
25 C12H26 dodecane
26 C5H10 1-pentene
27 C6H12 hex-1-ene
28 C7H14 1-heptene
29 C8H16 oct-1-ene
30 C9H18 1-nonene
31 C10H20 1-decene
32 C11H22 1-undecene
33 C12H24 1-dodecene
34 C6H12 cyclohexane
35 C6H10 cyclohexene
36 C6H8 1,3-cyclohexadiene
37 C12H19F6N3O4S2 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
38 CH4O methanol
39 C2H6O ethanol
40 C3H8O propan-1-ol
41 C4H10O butan-1-ol
42 C5H12O pentan-1-ol
43 C6H14O hexan-1-ol
44 C7H16O heptan-1-ol
45 C3H8O propan-2-ol
46 C4H10O 2-methyl-1-propanol
47 C4H10O butan-2-ol
48 C4H10O 2-methylpropan-2-ol
49 C5H12O 2-methylbutan-2-ol
50 C6H12O cyclohexanol
51 C6H6 benzene
52 C7H8 toluene
53 C8H10 ethylbenzene
54 C9H12 propylbenzene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 38
  • 37
  • Activity coefficient - 38 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 38; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 39
  • 37
  • Activity coefficient - 39 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 39; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 40
  • 37
  • Activity coefficient - 40 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 40; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 41
  • 37
  • Activity coefficient - 41 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 41; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 42
  • 37
  • Activity coefficient - 42 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 42; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 43
  • 37
  • Activity coefficient - 43 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 43; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 44
  • 37
  • Activity coefficient - 44 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 44; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 45
  • 37
  • Activity coefficient - 45 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 45; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 46
  • 37
  • Activity coefficient - 46 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 46; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 47
  • 37
  • Activity coefficient - 47 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 47; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 48
  • 37
  • Activity coefficient - 48 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 48; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 49
  • 37
  • Activity coefficient - 49 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 49; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 7
  • POMD
  • 50
  • 37
  • Activity coefficient - 50 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 50; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 51
  • 37
  • Activity coefficient - 51 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 51; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 9
  • POMD
  • 52
  • 37
  • Activity coefficient - 52 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 52; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 53
  • 37
  • Activity coefficient - 53 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 53; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 54
  • 37
  • Activity coefficient - 54 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 54; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 1
  • 37
  • Activity coefficient - 1 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 2
  • 37
  • Activity coefficient - 2 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 3
  • POMD
  • 3
  • 37
  • Activity coefficient - 3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 4
  • 37
  • Activity coefficient - 4 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 4; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 5
  • 37
  • Activity coefficient - 5 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 5; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 8
  • POMD
  • 6
  • 37
  • Activity coefficient - 6 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 6; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 7
  • 37
  • Activity coefficient - 7 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 7; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 8
  • 37
  • Activity coefficient - 8 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 8; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 9
  • 37
  • Activity coefficient - 9 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 9; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 10
  • 37
  • Activity coefficient - 10 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 10; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 11
  • 37
  • Activity coefficient - 11 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 11; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 12
  • 37
  • Activity coefficient - 12 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 12; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 13
  • 37
  • Activity coefficient - 13 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 13; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 14
  • 37
  • Activity coefficient - 14 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 14; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 7
  • POMD
  • 15
  • 37
  • Activity coefficient - 15 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 15; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 16
  • 37
  • Activity coefficient - 16 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 16; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 2
  • POMD
  • 17
  • 37
  • Activity coefficient - 17 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 17; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 8
  • POMD
  • 18
  • 37
  • Activity coefficient - 18 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 18; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 19
  • 37
  • Activity coefficient - 19 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 19; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 20
  • 37
  • Activity coefficient - 20 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 20; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 21
  • 37
  • Activity coefficient - 21 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 21; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 22
  • 37
  • Activity coefficient - 22 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 22; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 23
  • 37
  • Activity coefficient - 23 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 23; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 24
  • 37
  • Activity coefficient - 24 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 24; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 25
  • 37
  • Activity coefficient - 25 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 25; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 26
  • 37
  • Activity coefficient - 26 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 26; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 27
  • 37
  • Activity coefficient - 27 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 27; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 28
  • 37
  • Activity coefficient - 28 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 28; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 29
  • 37
  • Activity coefficient - 29 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 29; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 30
  • 37
  • Activity coefficient - 30 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 30; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 7
  • POMD
  • 31
  • 37
  • Activity coefficient - 31 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 31; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 8
  • POMD
  • 32
  • 37
  • Activity coefficient - 32 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 32; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 6
  • POMD
  • 33
  • 37
  • Activity coefficient - 33 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 33; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 8
  • POMD
  • 34
  • 37
  • Activity coefficient - 34 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 34; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 4
  • POMD
  • 35
  • 37
  • Activity coefficient - 35 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 35; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5
  • POMD
  • 36
  • 37
  • Activity coefficient - 36 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 36; Liquid
  • Liquid
  • Gas
  • Chromatography
  • 5