Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid-Liquid Equilibria on Three Binary Systems: Methyl Cyclopropanecarboxalate + Water; Dimethyl Sulfide + Water; and Dimethyl Disulfide + Water

Giles, N. F.[Neil F.], Wilson, G. M.[Grant M.]
J. Chem. Eng. Data 2006, 51, 6, 1963-1965
ABSTRACT
Liquid-liquid equilibria are reported at each of three temperatures for the following three binary systems: methyl cyclopropanecarboxalate + water; dimethyl sulfide + water; and dimethyl disulfide + water. These data were obtained by withdrawing and analyzing multiple samples from each of the two equilibrium liquid phases at each run temperature. No previously measured liquid-liquid equilibrium data were found in the literature for any of these three binary systems.
Compounds
# Formula Name
1 C5H8O2 cyclopropanecarboxylic acid, methyl ester
2 C2H6S 2-thiapropane
3 C2H6S2 2,3-dithiabutane
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 4
  • Mass fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 3
  • POMD
  • 1
  • 4
  • Mass fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 3
  • POMD
  • 2
  • 4
  • Mass fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 3
  • POMD
  • 2
  • 4
  • Mass fraction - 2 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 3
  • POMD
  • 3
  • 4
  • Mass fraction - 3 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 3
  • POMD
  • 3
  • 4
  • Mass fraction - 3 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 3