Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isochoric PVTx measurements for the C2H6 + N2O binary system

Corvaro, F.[Francesco], Di Nicola, G.[Giovanni], Pacetti, M.[Marco], Stryjek, R.[Roman]
J. Chem. Eng. Data 2006, 51, 1, 169-175
ABSTRACT
In the search for fluids potentially suitable for low-temperature refrigeration applications, we have turned our attention to systems consisting of natural fluids, nitrous oxide (N2O) and ethane (C2H6) in particular. Isochoric PVTx measurements are reported for nitrous oxide + ethane for both the two-phase and the superheated vapor regions at temperatures ranging from (216 to 358) K and pressures from (494 to 5261) kPa along 11 isochores. The data obtained in the two-phase region were used to derive VLE parameters using a flash method with the Carnahan-Starling-De Santis equation of state (CSD EOS). The dew point was also found for each isochore from the intersection of the P-T sequences. The dew points were then used to derive VLE parameters from CSD EOS. Results from the superheated region were compared with the predicted from the virial EOS and CSD EOS.
Compounds
# Formula Name
1 C2H6 ethane
2 N2O nitrous oxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Gas
  • Mole fraction - 1; Gas
  • Temperature, K; Gas
  • Gas
  • Liquid
  • ISOPVT
  • 11
  • POMD
  • 1
  • 2
  • Molar volume, m3/mol ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Gas
  • ISOCHOR
  • 128