Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Enthalpies of solution of glycine, L-alanine, and L-serine in water and aqueous solutions of LiNO3, NaNO3, and KNO3 were measured at 298.15 K. Enthalpies of transfer (trH) of amino acids from water to aqueous solutions of nitrate salts were derived. The effect of the ion type, concentration, and structure of amino acids on the magnitude of the transfer enthalpies are discussed in terms of the electrostatic interaction and the structural hydration interaction model.

Compounds

#	Formula	Name
1	C2H5NO2	2-aminoacetic acid
2	H2O	water
3	C3H7NO2	(S)-2-aminopropanoic acid
4	C3H7NO3	L-serine
5	NNaO3	sodium nitrate
6	KNO3	potassium nitrate
7	LiNO3	lithium nitrate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2	Apparent molar enthalpy, kJ/mol ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 1; Liquid		Liquid	CALVET:solid	1
POMD	3 2	Apparent molar enthalpy, kJ/mol ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 3; Liquid		Liquid	CALVET:solid	1
POMD	4 2	Apparent molar enthalpy, kJ/mol ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 4; Liquid		Liquid	CALVET:solid	1
POMD	1 5 2	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 1; Liquid	Liquid	CALVET:solid	9
POMD	1 2 6	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 6; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 1; Liquid	Liquid	CALVET:solid	9
POMD	1 2 7	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 7; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 1; Liquid	Liquid	CALVET:solid	9
POMD	3 2 7	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 7; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 3; Liquid	Liquid	CALVET:solid	9
POMD	3 5 2	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 3; Liquid	Liquid	CALVET:solid	9
POMD	3 2 6	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 6; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 3; Liquid	Liquid	CALVET:solid	9
POMD	4 2 7	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 7; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 4; Liquid	Liquid	CALVET:solid	9
POMD	4 5 2	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 5; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 4; Liquid	Liquid	CALVET:solid	9
POMD	4 2 6	Apparent molar enthalpy, kJ/mol ; Liquid	Solvent: Molality, mol/kg - 6; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid Molality, mol/kg - 4; Liquid	Liquid	CALVET:solid	9

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Enthalpies of Transfer of Amino Acids from Water to Aqueous Solutions of Alkali Metal Nitrates

Liu, C.[Chunli], Lin, R.[Ruisen], Xu, N.[Nan]

ABSTRACT