Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method

Chen, X.[Xu], Oja, V. [Vahur], Chan, W. G., Hajaligol, M. R.[Mohammad R.]
J. Chem. Eng. Data 2006, 51, 2, 386-391
ABSTRACT
The vapor pressures of anthracene, catechol, hydroquinone, caffeic acid, ferulic acid, gentisic acid, and myoinositol have been measured by an isothermal Knudsen effusion method. The vapor pressure correlations fit to the following linear equations: anthracene, ln(p/Pa) ) (31.886 +/- 0.440) to (11496 +/- 149) T/K (from 320 K to 354 K); catechol, ln(p/Pa) ) (31.05 +/- 0.18) to (9618+/-56) T/K (from 295 K to 310 K); hydroquinone, ln(p/Pa) ) (34.595 +/-0.455) to (12102 +/-150) T/K (from 327 K to 348 K); caffeic acid, ln(p/Pa) ) (45.122 +/- 1.320) to (20466 +/- 550) T/K (from 409 K to 424 K); ferulic acid, ln(p/Pa) ) (39.454 +/- 0.402) to (15925 +/-153) T/K (from 369 K to 390 K); gentisic acid, ln(p/Pa) ) (36.297 +/-0.454) to (14184+/- 168) T/K (from 362 K to 379 K); and myoinositol, ln(p/Pa) ) (44.366+/-0.702) to (20931 +/-315) T/K (from 438 K to 458 K). The sublimation enthalpies and entropies of these samples are calculated.
Compounds
# Formula Name
1 C14H10 anthracene
2 C9H8O4 caffeic acid
3 C6H6O2 1,2-benzenediol
4 C10H10O4 4-hydroxy-3-methoxycinnamic acid
5 C7H6O4 2,5-dihydroxybenzoic acid
6 C6H6O2 1,4-benzenediol
7 C6H12O6 cis-1,2,3,5-trans-4,6-cyclohexanehexol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 30
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 23
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 24
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 28
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 27
  • POMD
  • 6
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 27
  • POMD
  • 7
  • Vapor or sublimation pressure, kPa ; Crystal
  • Temperature, K; Crystal
  • Crystal
  • Gas
  • KNUDSEN:UFactor:2
  • 25