The solubilities of pentachloropyridine (PCP) and tetrachloropyridine (TECP) in methanol, ethanol, and 2-propanol were measured respectively using an analytical method from (293.15 to 355.15) K. From the thermodynamics theory of solid-liquid equilibrium, the solubility model was derived, and the experimental data were regressed. The average deviation of the model was smaller than 5 %. The fusion enthalpies (fusH) of PCP, TECP, and their infinite-dilution activity coefficientes (2) in methanol, ethanol, and 2-propanol were obtained by regressing the experimental data.
Compounds
#
Formula
Name
1
C5Cl5N
pentachloropyridine
2
C5HCl4N
2,3,5,6-tetrachloropyridine
3
CH4O
methanol
4
C2H6O
ethanol
5
C3H8O
propan-2-ol
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.