ABSTRACT

The liquid-liquid equilibrium in the aqueous biphasic system formed by water + propan-1-ol + cesium chloride and water + propan-2-ol + cesium chloride have been determined at (298.15, 308.15, and 318.15) K. The tie lines and binodal curves as well as refractive index were measured on solutions. The LLE equilibrium experimental data were correlated using Othmer-Tobias and Bancroft correlations. The effect of temperature on the liquid-liquid equilibria was insignificantly.

Compounds

#	Formula	Name
1	C3H8O	propan-1-ol
2	C3H8O	propan-2-ol
3	ClCs	cesium chloride
4	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 3 4	Refractive index (Na D-line) ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Crystal - 3 Liquid mixture 2	ABBE:UFactor:8	3
POMD	1 3 4	Refractive index (Na D-line) ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Crystal - 3 Liquid mixture 1	ABBE:UFactor:8	3
POMD	1 3 4	Mole fraction - 1 ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Crystal - 3 Liquid mixture 1	K2Cr2O7 oxidation	3
POMD	1 3 4	Mole fraction - 1 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Crystal - 3 Liquid mixture 2	K2Cr2O7 oxidation	3
POMD	1 3 4	Mole fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Crystal - 3 Liquid mixture 2	gravimetric	3
POMD	1 3 4	Mole fraction - 3 ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Crystal - 3 Liquid mixture 1	gravimetric	3
POMD	1 3 4	Refractive index (Na D-line) ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mole fraction - 3; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	ABBE:UFactor:8	12
POMD	1 3 4	Refractive index (Na D-line) ; Liquid mixture 2	Temperature, K; Liquid mixture 2 Mole fraction - 3; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Liquid mixture 1	ABBE:UFactor:8	12
POMD	1 3 4	Mass fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 1; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	TITR:UFactor:2	45
POMD	1 3 4	Mole fraction - 1 ; Liquid mixture 2 Mole fraction - 3 ; Liquid mixture 1 Mole fraction - 1 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mole fraction - 3; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	K2Cr2O7 oxidation K2Cr2O7 oxidation K2Cr2O7 oxidation	12
POMD	2 3 4	Refractive index (Na D-line) ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Crystal - 3 Liquid mixture 1	ABBE:UFactor:8	3
POMD	2 3 4	Refractive index (Na D-line) ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Crystal - 3 Liquid mixture 2	ABBE:UFactor:8	3
POMD	2 3 4	Mole fraction - 2 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Crystal - 3 Liquid mixture 2	K2Cr2O7 oxidation	3
POMD	2 3 4	Mole fraction - 2 ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Crystal - 3 Liquid mixture 1	K2Cr2O7 oxidation	3
POMD	2 3 4	Mole fraction - 3 ; Liquid mixture 2	Temperature, K; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Crystal - 3 Liquid mixture 1	gravimetric	3
POMD	2 3 4	Mole fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Crystal - 3 Liquid mixture 2	gravimetric	3
POMD	2 3 4	Refractive index (Na D-line) ; Liquid mixture 2	Temperature, K; Liquid mixture 2 Mole fraction - 3; Liquid mixture 2	Pressure, kPa; Liquid mixture 2	Liquid mixture 2 Liquid mixture 1	ABBE:UFactor:8	12
POMD	2 3 4	Refractive index (Na D-line) ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mole fraction - 3; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	ABBE:UFactor:8	12
POMD	2 3 4	Mass fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 2; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	TITR:UFactor:2	44
POMD	2 3 4	Mole fraction - 2 ; Liquid mixture 2 Mole fraction - 3 ; Liquid mixture 1 Mole fraction - 2 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mole fraction - 3; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	K2Cr2O7 oxidation K2Cr2O7 oxidation K2Cr2O7 oxidation	12

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Equilibrium Phase Behavior of Water + Propan-1-ol or Propan-2-ol + Cesium Chloride at (298.15, 308.15, and 318.15) K

Hu, M.[Mancheng], Jin, L.[Lihua], Li, S.[Shuni], Jiang, Y.[Yucheng]

ABSTRACT